The Largest Independent Automotive Research Resource
The Misguided War of the Elements - BEV, EV, or H2 Fuel Cells?
Instead of Thinking “Either/Or,” We Should be Thinking “Yes, And…”
Introduction and Summary
Nearly 150 years ago, Thomas Edison and George Westinghouse fought a battle for the supremacy of Direct Current (DC) vs. Alternating Current (AC) known as the
War of the Currents.
Not only was the War of the Currents full of false accusations and intrigue, but the war’s short-term winner — AC — did not become the singular best solution in the long run. As vacuum tubes, then semiconductors, grew more common, DC took on an increasing role in the electrical chain from power generation to end-use. Today, both types of power — DC and AC — are used wherever each works best. AC is still used between power plants and buildings. But electronic equipment, including LED lighting, computers, and inverter-driven motors, increasingly convert AC to DC before use, while renewable power generation and storage increasingly converts from DC to AC.
Like the War of the Currents 150 years ago, today another war is being imagined — a “War of the Elements” for energy storage and transport, between hydrogen, as used in fuel cells and engines, and lithium, as used in lithium-ion batteries.
With the benefits of 150 years of hindsight, what lesson can we apply from Edison and Westinghouse’s War of the Currents to today’s imagined War of the Elements?
It is that diversity is a better solution than monoculture.
Lithium, when used in lithium-ion batteries, has high energy efficiency and uses existing charging infrastructure, but has low energy per mass and limited charging rate, making it impractical for large vehicles.
By contrast, Hydrogen, as used in hydrogen fuel cells and engines, has high energy per mass and a high charging rate, but lower energy efficiency and needs new charging infrastructure. In contrast to lithium-ion batteries, hydrogen particularly excels in large vehicles.
Each approach has its benefits and its drawbacks, and each is strong where the other is weak:
If we understand the complementary advantages of Lithium and Hydrogen, and the 150-year-old lessons from the War of the Currents, there is no need to pick a winner now, and no reason to impose a single winner when the likely best solution will be both, depending on circumstances.
In other words, there’s no need for a war at all.
Like my previous blog entries about the advantages of vehicle drivetrain diversity, the same universal lessons apply to energy storage and transport:
Diverse circumstances require diverse solutions,
What is best for the average is not best for all, and
The solution to uncertainty is diversity.
Instead of thinking “either/or” we should be thinking “yes, and…”
This is why Toyota is continuing to invest R&D resources in a wide range of possible energy storage and transport technologies. We believe that by doing so, instead of prematurely picking singular winners, the best possible diverse solutions, suited to a diverse range of applications, will emerge.
The Basics: Hydrogen
Hydrogen is the simplest and lightest element and is the most common element in the universe. Hydrogen is non-toxic, and when it reacts with oxygen releases significant amounts of energy and produces pure water:
2 H2 + O2 ⇌ 2 H2O + 572 kJ of energy
The energy released from this reaction can be in the form of heat (which can run a steelmaking furnace or power an engine), or electricity from a fuel cell, shown below.
If the fuel cell above looks a little like a battery, it’s no accident — both fuel cells and battery cells exploit similar physics to convert between chemical and electrical energy, except in fuel cells energy is stored externally in a tank, whereas in battery cells energy is stored inside the battery itself.
Since oxygen is plentiful in the air around us and also free, we need only store and transport hydrogen to store and transport energy.
Hydrogen has both advantages and drawbacks. Because of hydrogen’s low boiling point at normal pressure (20 degrees Kelvin which is super cold), it is harder to store and transport than room temperature liquid fuels like gasoline. Small molecules like hydrogen tend to leak from pipe fittings and
can also penetrate the surface of inexpensive metals, making them brittle. Luckily, hydrogen is light and dissipates very rapidly and alternative materials are impervious to hydrogen. We’ll talk about hydrogen’s comparative efficiency shortly.
Lithium sits directly underneath hydrogen on the periodic table and is the lightest solid element at room temperature and pressure.
Lithium is around 500 times rarer on earth than hydrogen, but around 20 times more plentiful than other elements like nickel and cobalt that are also used in some lithium-ion batteries. Large reserves of lithium exist in South America, Australia, and other parts of the world.
Like hydrogen, lithium can be oxidized to release heat, but this is a disadvantage because when lithium is mixed with water, it produces hydrogen gas, which is flammable. This is why trying to put out a lithium-based battery fire with water makes things worse.
The real advantage of lithium is when it is used in battery cells. They work like fuel cells, but with internal instead of external storage of energy, as shown below:
Performance: Energy per Mass (i.e. Specific Energy)
As seen in the table above, hydrogen stores very high amounts of chemical energy per mass — more than 100 times the electrical energy in the active parts of lithium-ion battery cells. This is why lithium-ion batteries are not practical for long-range aircraft — they simply weigh too much — and why hydrogen is a common rocket fuel.
Because of hydrogen’s very high energy per mass, the fuel tank of the Toyota Mirai carries only a tiny mass — 5 kg (11 lbs) — of hydrogen fuel, yet can power the Mirai over 400 miles between refuelings. In fact, a Mirai just set a world record of 845 miles on one load of fuel.
Of course, to do a fair comparison, we must also take into account the additional mass beyond the active energy storage elements of each system.
For example, the 2021 Toyota Mirai FCEV weighs a few hundred pounds less than the similar size and range Tesla Model S long-range Battery Electric Vehicle (BEV). And a gasoline-powered Internal Combustion Engine (ICE) Camry weighs a few hundred pounds less than the Mirai.
Beyond hydrogen’s lower mass, the much larger mass of lithium-ion batteries needed by a long-range passenger car BEV consumes more natural resources, emits more carbon during manufacture, and is likely more costly to recycle than the equivalent equipment in an FCEV or Plug-In Hybrid Electric Vehicle (PHEV). And, because lithium-ion batteries are still improving and will be supply-limited for some time, placing many
lithium-ion batteries into fewer long-range BEVs rather than many more smaller-battery FCEVs and PHEVs can result in less total carbon emissions reduction.
As vehicle size scales up, the 100X higher energy per mass of hydrogen gives hydrogen a much greater mass advantage in trucks, trains, ships, long-range aircraft (shown above), and spacecraft.
A hydrogen tank can be recharged 10–100 times faster than lithium-ion batteries without the lifetime degradation suffered by rapidly charged lithium-ion batteries. This advantage becomes critical in larger vehicles like trucks, trains, planes, and ships, which must quickly replenish much larger reserves of energy.
Because the energy content of chemical fuels is so high, the rate of energy transfer when a car’s fuel tanks are being filled with gasoline or hydrogen is 1–10 MegaWatts (MW). That’s 10–100 times the power of a 100kW level 3 DC BEV Supercharger. This is why it takes so much less time to fill up a car’s fuel tank (gasoline or hydrogen) than to fully recharge a BEV’s empty batteries.
Will this improve in the future?
Our research on solid-state batteries is aimed at just that. But even if the battery problem is solved, supplying several MW of electrical power to many individual recharging stalls will be very challenging. The electrical grid was not designed to deliver that much power to that many individual locations and will need substantial enhancement.
To understand why, consider this: The amount of energy stored in each gas station’s tanks is also extraordinarily high — enough to fully fill thousands of car’s fuel tanks, i.e several hundred MWh per station. There is no equivalent local storage in the electrical power grid. And a tanker truck unloads fuel into a station’s tanks at hundreds of gallons per minute — the equivalent of hundreds of MW of power — the level of power generated by a small nuclear reactor. Again, there is presently no equivalent in the electrical power grid.
To counteract the much slower recharge time of batteries compared to gasoline, Tesla pioneered the idea of overlapping time during supercharging, with passengers taking a break to eat or shop while their BEV is recharging. I have enjoyed doing this with my model X on long trips, but doing it often shortens the life of the battery and ties up a high capital resource — the supercharger.
Charging at Home
In parts of the world with low population density (e.g. the US), and lots of at-home overnight off-street parking (e.g. US suburbs), light-duty electric vehicles will mostly be charged every evening at home.
However, the vast majority of the population worldwide are city dwellers, and
those with cars must often park them on the street or in dense public garages some distance from their homes without access to electrical power and associated personalized billing systems. It will take significant time and capital to provide such facilities for every vehicle parked overnight in cities. Until then, rapid charging/refueling will still be desirable.
Commercial and Heavy Vehicles
Commercial vehicles differ from light-duty vehicles because they travel much longer distances with much less time available for recharging, and are much larger (and energy-intensive) than passenger vehicles. Unlike a passenger car, which typically holds 15 gallons of fuel, a semi-truck holds hundreds of gallons. The required electrical power to recharge a truck in a short period of time is so high as to likely be impractical. Battery swap solutions are one approach, but long-range BEV batteries are heavy, and long-range batteries for truck BEVs are extremely heavy, making swapping very difficult. Other researchers have come to similar conclusions.
Which geographic, economic, and environmental circumstances will favor hydrogen vs. lithium for lightweight passenger vehicles is uncertain. But when vehicles get large, the scales tip substantially in the direction of hydrogen. This is why we are working so hard on our Port of Los Angeles 18 Wheeler program, illustrated above, and why there are also strong advantages for hydrogen in larger vehicles like trains (around 5000 gallons of diesel per locomotive fuel tank), long-range aircraft (a 787 has a fuel capacity on the order of a car filling station — over 30,000 gallons), and ships (that typically hold millions of gallons of highly polluting heavyweight “bunker” fuel). In the case of ships, it may be best to combine hydrogen with nitrogen to make ammonia.
High round-trip energy efficiency is one of the strengths of lithium-ion batteries. Compared to chemically fueled engines, both lithium-ion batteries and hydrogen are more energy efficient. But generating hydrogen from electricity, compressing and storing it in a tank, and converting it back into electricity, loses around twice the amount of energy that is lost directly charging and discharging lithium-ion batteries.
In some systems where energy loss must be minimized, lithium-ion batteries tend to be a better choice.
In other systems, including some renewable energy ones, total cost is more important than energy efficiency. For example, the solar cells chosen for large commercial photovoltaic power stations are only about half as energy-efficient as the most energy-efficient solar cells available.
Because the cost of the land underneath the solar cells is low, using larger, less energy-efficient — but also less costly — solar cells above and more land below can result in lower net cost for each kWh of energy produced.
In a similar way, because the cost of renewable energy has dropped so much, the lower energy efficiency of hydrogen may be a less important factor. The energy shortages of the past taught us to value energy efficiency. But today energy supplies are plentiful while reducing greenhouse gas emissions and cost are more important. Energy efficiency isn’t everything.